Abstract

Abstract : The electron diffraction sector method was used to determine the structure of the butatriene molecule in the vapour phase. The error limits of all the parameters are approximately + or 0.005 angstroms. As in several other molecules with linear equilibrium conformation, a shrinkage effect is observed; i.e. the observed non bonded CC distances are a trifle shorter than that calculated from the sum of the individual bond distances. The effect is explained by outof-linearity vibrations. (Author)

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