Abstract
Summary The electrochemical behavior of KWCl 6 , K 2 WCl 6 , WCl 5 bipy, WCl 5 (py) 2 , and WCl 4 bipy in acetonitrile has been investigated. WCl 5 bipy and WCl 5 (py) 2 were shown to give the WCl 6 − ion and unidentified unstable cationic species in solution. Substitution of chloride by the π-acceptor 2,2′-bipyridine results in the stabilization of the lower oxidation states, +3 and +2, of tungsten.
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