Abstract

AbstractThe coupling reaction of epoxides and CO2 is in the focus of many research activities in academia as well as in the industry. In this contribution we report on a versatile aluminum‐based homogeneous catalyst utilizing an easy‐to‐synthesize N2O2 ligand system in combination with various cocatalysts, all of them producing pure alternating poly(cyclohexene carbonate)s with Mn values in the range 10000–15000 g mol–1. This system also efficiently catalyzes the formation of propylene carbonate.

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