Abstract
We report here 4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene (SiDT) as an electron donor to construct a donor-acceptor type conjugated polymer (PSiDT-BTDO) photocatalyst with a narrow band gap by employing dibenzo[b,d]thiophene-S,S-dioxide as an electron acceptor. The resulting polymer PSiDT-BTDO could realize a high hydrogen evolution rate of 72.20 mmol h-1 g-1 under ultraviolet-visible light with a Pt co-catalyst, due to the enhanced hydrophilicity as well as the decreased recombination rate of photo-induced holes/electrons and the dihedral angles of the polymer chains. The high photocatalytic activity of PSiDT-BTDO reveals the promising application of the SiDT donor in designing high-performance organic photocatalysts for hydrogen evolution.
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