Abstract

Selective mono-functionalization of 1,1,3,3-tetramethyldisiloxane (TMDSO) with olefins via hydrosilylation reaction is reported. On the basis of a study of platinum- and rhodium complexes in the reactions between TMDSO and selected olefins containing C=C bond, it was possible to choose the most efficient catalyst whose application in the solvent-free system led to selective mono-functionalization of the disiloxane reagent and simultaneous formation of only β-regioisomeric products, bearing in their structure functional groups of unique reactivity or physicochemical properties.

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