Abstract

1,3-Dipolar cycloaddition between aromatic selenoaldehydes, generated by thermal retro Diels–Alder reaction of anthracene cycloadducts, and nitrile oxides or nitrile imines proceeded efficiently to give the corresponding [3+2] cycloadducts as a single isomer in good yields, being 1,4,2-oxaselenazoles or 1,3,4-selenadiazoles, respectively.

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