Abstract

In the present research paper, a biosorptive remediation practice for an aqueous medium sample polluted with manganese ions was implemented using the activated coastal waste of the Zostera marina plant. This is the first report in the literature on the utilization of current modified biological waste as a biosorbent substance for the removal of manganese ions from the water environment. The analyses of biosorbent characterization, environmental condition, kinetic, equilibrium, and comparison were performed to introduce the ability of prepared biosorbent for the removal of manganese from the aquatic medium. The biosorbent matter has a rough surface with numerous cavities and cracks and various functional groups for the biosorption of manganese. The environmental conditions significantly affected the manganese purification process, and the optimum working conditions were determined to be biosorbent quantity of 10 mg, pH of 6, manganese concentration of 30 mg L−1, and time of 60 min. The pseudo-second-order model best explained the kinetic data of biosorption operation. The biosorption equilibrium data were best described by the Freundlich isotherm. According to the Langmuir equilibrium model, the maximum purification potency was estimated to be 120.6 mg g−1. The comparison work revealed that the activated coastal waste of the Z. marina plant could be utilized as an effectual and promising biosorbent substance for the remediation of an aquatic environment contaminated with manganese ions.

Highlights

  • Today, heavy metal pollution is a leading environmental trouble worldwide because of the severe noxious effects of heavy metal ions to human beings and natural ecosystems [1]

  • Considerable amounts of heavy metal ions are frequently released into the receiving environment, especially the water environment without proper clarification [2, 3]

  • The coastal waste of the Z. marina plant was supplied from the region of Black Sea (Sinop, Turkey)

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Summary

Introduction

Heavy metal pollution is a leading environmental trouble worldwide because of the severe noxious effects of heavy metal ions to human beings and natural ecosystems [1] These substances are widely used in different industrial activities like plating, smelting, tanning, mining, plastic, alloy, electronic, paint, tire, fertilizer, battery, ceramic, and agrochemical production processes. Considerable amounts of heavy metal ions are frequently released into the receiving environment, especially the water environment without proper clarification [2, 3]. These metallic elements are toxic, carcinogenic, accumulative, stubborn, and nondegradable [1, 4].

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