Abstract
Heterotrinuclear Ti–Cu–Ru ( 5) and heterotetranuclear Ti–Cu–Pt–Fe ( 7) containing complexes are accessible by using {[Ti](CC tBu) 2}CuMe ( 1) ([Ti]=( η 5-C 5H 4SiMe 3) 2Ti) as key molecule; in 5 and 7, the corresponding early and late transition metal atoms are linked by π-conjugated organic moieties.
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