Abstract
Trimethylsilyloxy and ethoxy iminyls (4a-i) have been generated by photolysis of solutions of the corresponding trimethylsilyl and ethyl N- chloro imidates , in the cavity of an e.s.r. spectrometer. The unpaired electron resides in a 2py orbital on nitrogen in concurrence with the results of MNDO and INDO calculations. The bimolecular rate constants for decay of trimethylsilyloxy t-butyl iminyl (4c) have been evaluated. Trimethylsilyloxy 1,l-dimethylbut-3-enyl iminyl (4e) undergoes an N-C δ cyclization.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
