Abstract

Sulfur Kα 1,2 X-ray transitions are calculated for a series of systems using the equivalent-cores approximation in which sulfur with a core hole is replaced by a Cl + ion. Charge densities on such chlorine atoms are evaluated using the INDO method and correlated with experimental transition energies. The position of Kα 1,2 lines which cannot be resolved experimentally are predicted. A qualitative explanation of valence orbital penetration into the atomic core and the resulting effects on X-ray spectra is presented.

Full Text

Published Version

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.