Abstract

Calculations of total and total subshell cross sections together with corresponding asymmetry parameters have been performed for CO, CO 2 and N 2O using the ground state inversion potential method with (GIPM/D) or without (GIPM/A) allowing for multicentre interference effects. Results are presented for valence and inner valence orbitals for photon energies from threshold to ≈ 80 eV. Attention is focused on the molecularity imparted to the orbital cross sections due to the interference effects and the correlation of these effects with the bonding type of the orbital. Similarities between cross sections of appropriately paired orbitals of the different molecules are discussed.

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