Abstract

The development of a highly sensitive ammonia sensor is described. The sensor is formed by deposition of a nanoscale coating of titanium dioxide, containing a porphyrin as a functional material, onto a tapered optical fibre. The titanium dioxide coating allows coupling of light from the fundamental core mode to a lossy mode supported by the coating, thus creating a Lossy Mode Resonance (LMR) in the transmission spectrum. A change in the refractive index of the coating caused by the interaction of the porphyrin with ammonia causes a change in the centre wavelength of the LMR, allowing concentrations of ammonia in water as low as 0.1ppm to be detected, with a response time of less than 30s.

Highlights

  • An ammonia sensor based on Lossy Mode Resonances on a tapered optical fibre coated with porphyrin-incorporated titanium dioxide

  • The sensor is formed by deposition of a nanoscale coating of titanium dioxide, containing a porphyrin as a functional material, onto a tapered optical fibre

  • The titanium dioxide coating allows coupling of light from the fundamental core mode to a lossy mode supported by the coating, creating a Lossy Mode Resonance (LMR) in the transmission spectrum

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Summary

17 November 2016

The development of a highly sensitive ammonia sensor is described. The sensor is formed by deposition of a nanoscale coating of titanium dioxide, containing a porphyrin as a functional material, onto a tapered optical fibre. The titanium dioxide coating allows coupling of light from the fundamental core mode to a lossy mode supported by the coating, creating a Lossy Mode Resonance (LMR) in the transmission spectrum. A change in the refractive index of the coating caused by the interaction of the porphyrin with ammonia causes a change in the centre wavelength of the LMR, allowing concentrations of ammonia in water as low as 0.1 ppm to be detected, with a response time of less than 30 s

Introduction !
Tapered optical fibre fabrication
Preparation of sensing layers and ammonia sensing
Experimental setup
Results and discussion
LMR generation
Ammonia sensing
Conclusions !
Full Text
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