Abstract
Facile access to dimeric heavier aluminum chalcogenides [(NHC)Al(Tipp)-μ-Ch]2 (NHC=IiPr (1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene, IMe4 (1,3,4,5-tetramethylimidazol-2-ylidene); Tipp=2,4,6-iPr3 C6 H2 ; Ch=Se, Te) by treatment of NHC-stabilized aluminum dihydrides with elemental Se and Te is reported. The higher affinity of IMe4 in comparison with IiPr toward the Al center in [(NHC)Al(Tipp)-μ-Ch]2 can be used for ligand exchange. Additionally, the presence of excess IMe4 allows for cleavage of the dimers to form a rare example of a neutral multiply bonded heavier aluminum chalcogenide in the form of a tetracoordinate aluminum complex, (IMe4 )2 (Tipp)Al=Te. This species reacts with three equivalents of CO2 across two Al-CNHC and the Al=Te bond affording a pentacoordinate aluminum complex containing a dianionic tellurocarbonate ligand [CO2 Te]2- , which is the first example of tellurium analogue of a carbonate [CO3 ]2- .
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