Abstract
The derivation of the Allen-Cahn and Cahn-Hilliard equations is based on the Clausius-Duhem inequality. This is not a derivation in the strict sense of the word, since other phase field equations can be fomulated satisfying this inequality. Motivated by the form of sharp interface problems, we formulate such an alternative equation and compare the properties of the models for the evolution of phase interfaces in solids, which consist of the elasticity equations and the Allen-Cahn equation or the alternative equation. We find that numerical simulations of phase interfaces with small interface energy based on the alternative model are more effective then simulations based on the Allen-Cahn model.
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