An Algal Removal Using a Combination Of Flocculation and Flotation Processes

Abstract

The paper describes certain facets of the removal of the algae (Scenedesmus quadricauda) from water, using a froth flotation separation method, in conjunction with two types of surfactants, (cetyltrimethylammonium bromide) CTAB and (sodium dodecylsulfate) SDS. A 90% algal removal efficiency was achieved when 100 mg l-1 of CTAB was used whereas for the SDS solutions, the same concentration gave, by comparison, a very poor algal removal efficiency. An addition of 1 mg l–1 of a commercial cationic polyelectrolyte, which was the optimal concentration as was evident from the zeta potential and the particle size distribution measurements, prior to the SDS addition resulted in a formation of algal flocs and consequently a substantial improvement in the extent of the algal removal. A 50 mg l-1 solution of SDS was found to be the optimal concentration to completely remove these algal flocs from water. The amount of water removed along with the algal flocs, produced using 1 mg l-1 of the commercial polyelectrolyte and subsequently removed using SDS, was comparatively lower than that removed with the algal cells when CTAB was used as the 'collector'. It was generally found, in this study, that an addition of the polyelectrolyte improved the removal efficiencies and the rate of separation and also decreased the amount of the associated water removed along with the algal sludge.