Abstract

Thermal desorption spectroscopy (TDS), adsorption-desorption equilibrium (ADE), adsorption transient (AT) and desorption transient (DT) measurements are used to study the adsorption and condensation of Cu on Mo(110). Fitting the ADE results with various statistical-mechanical models gives good agreement with the desorption energies derived from the TDS, AT, and DT measurements. At coverages above two monolayers (ML) three-dimensional nucleation is seen in the kinetic measurements.

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