Abstract

We report an unusual phenomenon in amplified spontaneous emission (ASE) from cyano-substituted oligo(p-pheny lenevinylene) (CNDPASDB) single crystals, i.e., the ASE peak wavelength, exhibits varied dependence on the pumping wavelength λex. The former is basically kept a constant when λex<505 nm, while a rapid redshift from 560 to 572 nm occurs when λex>505 nm. The observation is different from stimulated Raman resonant scattering (SRRS) in two following aspects: the nonconstant Stokes shift and a much broader emission linewidth. A model describing competition between the stimulated emission and vibration relaxations has been proposed to interpret the underlying mechanism.

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