Abstract

AbstractPolysaccharide coatings are of interest for marine antifouling applications because of their good marine antifouling properties and environmentally benign characteristics. However, the hydrophilic nature of polysaccharide coatings can lead to the adsorption of marine sediment, which can negatively impact their antifouling properties. Amphiphilic modification of polysaccharide coatings has been demonstrated to address these issues. In this study, we report a simple method for post‐modification of a sulfated polysaccharide carrageenan (CAR) coating to make it amphiphilic. A hydrophilic CAR coating is first formed on solid substrates, followed by grafting hydrophobic molecules onto the CAR‐coated surfaces through metal‐ion‐mediated coordinate bond formation. The resulting amphiphilic CAR coating effectively reduces both marine sediment (silt) adsorption and marine diatom adhesion, achieving a balanced marine antifouling performance.

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