Amphiphilic Polymers for Color Dispersion: Toward Stable and Low-Viscosity Inkjet Ink.

Abstract

Amphiphilic random and block copolymers were synthesized as potential inkjet inks. This study evaluated the potential of these polymers for color dispersion by examining the following factors: surface tension, zeta potential, viscosity, and particle size. Acrylic acid and (ethoxyethoxy)ethyl acrylate were used as the hydrophilic molecular units. Styrene, butyl acrylate, and phenoxyethyl acrylate were used as hydrophobic units. Color dispersions were prepared by using organic dye and these amphiphilic polymers. The color dispersions containing random copolymers exhibited low viscosity, which is preferable for jetting, but the dye particles tended to sediment after the thermal aging test. In contrast, those containing block copolymers showed high viscosity, which was unsuitable for jetting. However, they retained their initial dispersion state after the aging test. The advantages and disadvantages of each monomer arrangement (random or block) were demonstrated, providing a future outlook on the molecular design of polymer dispersants for color dispersions.