Amphiphilic ionic liquid assembly route for the synthesis of polymer/Ag spheres and Ag-decorated bimodal porous silica

Abstract

The multifunctional assembly of amphiphilic ionic liquids (AILs) can play an important role in the synthesis of various composite nanomaterials. In this work, we developed a novel strategy to steer the generation of polymer/AIL16/Ag spheres by using amphiphilic ionic liquid, 1-hexadecyl-3-methylimidazolium chloride (AIL16) as a “bridge”. Two kinds of polymer spheres (poly(methyl methacrylate), PMMA or polystyrene, PS) were used to assemble of the PMMA/AIL16/Ag (or PS/AIL16/Ag) microspheres. Subsequently, the PMMA/AIL16/Ag (or PS/AIL16/Ag) microspheres and AIL16 were used as templating agents of macropores and mesoporores respectively to prepare Ag-decorated bimodal porous silica. The effects of mass ratios of m(Ag)/m(PMMA, or PS) and amount of AIL16 on the formation of the PMMA (or PS)/AIL16/Ag microspheres and the Ag-decorated bimodal porous silica structure were investigated in detail. It was found that the dispersity and loading capacity of Ag nanoparticles onto the polymer spheres and the structures of the bimodal porous silica can be easily manipulated by changing the mass ratios of m(Ag)/m(PMMA, or PS) and the amount of adding AIL16. The obtained Ag-decorated bimodal porous silica exhibited three dimensional ordered spherical macroporous array with an ordered mesoporous silica walls, in which Ag-NPs with good dispersibility were immobilized onto the inner walls of the macroporous holes. Furthermore, the synthesized Ag-decorated bimodal porous silica displayed a better catalytic activity for the reduction reaction of 4-nitrophenol by using NaBH4 as reducer.