Abstract
Efficient separation of aromatic amine isomers is a challenging issue in chemical industry and environmental analysis. Here we report the use of p-amino-tetradecyloxy-calix[4]arene (C4A-NH2) as a novel stationary phase for gas chromatographic (GC) separations. The statically coated C4A-NH2 capillary column showed a high column efficiency of 4332 plates/m for a 0.25 mm ID column and medium polarity. The C4A-NH2 stationary phase exhibited an excellent separation performance both for aromatic amine isomers and a complex mixture of aliphatic analytes with a wide ranging polarity, showing distinct advantages over the commercial polysiloxane stationary phases via diversified molecular interactions covering H-bonding, π-π, van der Waals interactions and shape-fitting selectivity. The retention mechanisms of aromatic amine isomers on C4A-NH2 column were further investigated by quantum chemistry calculations. In addition, the C4A-NH2 column showed good column repeatability with relative standard deviation (RSD) values of 0.03%-0.07% for run-to-run, 0.10%-0.27% for day-to-day and 2.6%–5.7% for column-to-column, respectively, and thermal stability up to 240℃.
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