Abstract
Developing high-efficiency durable electrocatalysts in wide pH range for water splitting is significant for environmentally-friendly synthesis of renewable hydrogen energy. Herein, a facile method by dealloying designable multicomponent metallic glass precursors is reported to synthesize amorphous-crystalline heterostructured nanoporous high-entropy alloys (AC-HEAs) of CuAgAuPtPd, CuAgAuIrRu, and CuAgAuPtPdIrRu, heaped up by nanocrystalline particles with an average size of 2-3nm and the amorphous glued phase. The synthesized AC-HEA-CuAgAuPtPd owns highly catalytic performances for hydrogen evolution reaction (HER), with 9.5 and 20mV to reach 10 mA·cm-2 in 0.5m H2SO4 and 1.0m KOH, and AC-HEA-CuAgAuIrRu delivers 208 and 200mV for oxygen evolution reaction (OER). Moreover, a two-electrode electrolyzer made of the AC-HEA-CuAgAuIrRu bifunctional electrodes exhibit a low cell voltage of 1.48 and 1.49V in the acidic and alkaline conditions at 10 mA·cm-2 for overall water splitting. Combining the enhanced catalytic activities from nanoscale amorphous structure and atom-level synergistic catalyst in AC-HEAs provides an effective pathway forpH-universal electrocatalysts of water splitting.
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