Ammonia sensor based on polypyrrole–graphene nanocomposite decorated with titania nanoparticles

Abstract

A composite of polypyrrole (PPy) and graphene nanoplatelets (GNs) decorated with titanium dioxide (TiO2) nanoparticles (TiO2@PPy–GN) was synthesized by a sol–gel process combined with in situ chemical polymerization. The microstructure, morphology, and crystallinity of the TiO2@PPy–GN nanocomposite were characterized by Fourier-transform infrared spectrometry, scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. The results indicate that the TiO2 nanoparticles with a diameter of 10–30nm were well dispersed on the PPy–GN composite. The TiO2@PPy–GN nanocomposite exhibited good electrical-resistance response to NH3 at room temperature. Compared to the PPy–GN thin film, the TiO2@PPy–GN thin film showed enhanced NH3-sensing properties in the form of higher sensitivity and much faster response under the same conditions. The selectivity and stability of the NH3 sensor based on theTiO2@PPy–GN nanocomposite were also investigated.