Ammonia removal from leachate solution using natural Chinese clinoptilolite

Abstract

This paper assesses the potential of natural Chinese clinoptilolite for ammonia removal from the leachate solution of sewage sludge. In batch study the effects of relevant parameters, such as contact time, initial ammonia concentration and particle size of clinoptilolite, were examined respectively. The results show that the data obtained from batch studies were fit to Langmuir and Freundlich isotherms and the Langmuir isotherms reflect more reasonable for ammonium ion uptake onto clinoptilolite; the clinoptilolite adsorption process has been proved effective, at laboratory scale, the maximum adsorption capacity of the clinoptilolite, for ammonium concentration ranging from 11.12 to 115.16 mg NH 4–N L −1 in leachate solution, was about 1.74 mg NH 4–N g −1; the time to adsorption equilibrium was 2.5 h in leachate solution and 1.5 h more than for in NH 4Cl synthetic solution; ammonium adsorption increased with decreasing clinoptilolite particle size; the ammonia removal capacity of clinoptilolite increased with increasing initial ammonia concentration. It is believed that as adsorption agent for NH 4–N removal from sludge leachate, natural Chinese clinoptilolite can be feasible.