Abstract
In the title compound, [Ru(CO)(NH3)(C9H10BN6)(C18H15P)]Cl·2CH2Cl2, the coordination environment around the RuII atom is distorted octahedral. One of the Ru—N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N—H⋯Cl hydrogen bonds link the complex cations and Cl− anions. π–π interactions between the pyrazole rings [centroid–centroid distance = 3.764 (3) Å] are also present.
Highlights
Mo K radiationR factor = 0.045; wR factor = 0.119; data-to-parameter ratio = 15.0
Hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
R factor = 0.045; wR factor = 0.119; data-to-parameter ratio = 15.0. In the title compound, [Ru(CO)(NH3)(C9H10BN6)(C18H15P)]Cl2CH2Cl2, the coordination environment around the RuII atom is distorted octahedral. Hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. N—H Cl hydrogen bonds link the complex cations and Cl anions. – interactions between the pyrazole rings [centroid–centroid distance =. For general background to complexes with hydridotris(pyrazolyl)borate ligands, see: Alcock et al (1992); Burrows (2001); Chen et al (2010); Lin et al (2008); Lo et al (2010); Pavlik et al (2005); Tong et al (2008).
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