Abstract
Q-band and X-band pulsed electron paramagnetic resonance spectroscopic methods (EPR) in the solid state were employed to refine the parameters characterizing the anisotropic interactions present in six nitroxide radicals prepared by N,N addition of NO to various borane-phosphane frustrated Lewis pairs (FLPs). The EPR spectra are characterized by the g-anisotropy as well as by nuclear hyperfine coupling between the unpaired electron and the 11B/10B, 14N and 31P nuclear magnetic moments. It was previously shown that continuous-wave spectra measured at X-band frequency (9.5 GHz) are dominated by the magnetic hyperfine coupling to 14N and 31P, whereas the g-tensor values and the 11B hyperfine coupling parameters cannot be refined with high precision from lineshape fitting. On the other hand, the X-band electron spin echo envelope modulation (ESEEM) and hyperfine sublevel correlation (HYSCORE) spectra are completely dominated by the nuclear hyperfine coupling to the 11B nuclei, allowing a selective determination of their interaction parameters. In the present work this analysis has been further validated by temperature dependent ESEEM measurements. In addition, pulsed EPR data measured in the Q-band (34 GHz) are reported, which present an entirely different situation: the g-tensor components can be measured with much higher precision, and the ESEEM and HYSCORE spectra contain information about all of the 10B, 11B, 14N and 31P hyperfine interaction parameters. Based on these new results, we report here high-accuracy and precision data of the EPR spin Hamiltonian parameters measured on six FLP-NO radical species embedded in their corresponding hydroxylamine host structures. While the ESEEM spectra at Q-band frequency turn out to be very complex (due to the multinuclear contribution to the overall signal) in the HYSCORE experiment the extension over two dimensions renders a better discrimination between the different nuclear species, and the signals arising from hyperfine coupling to 10B, 11B, 14N and 31P nuclei can be individually analyzed.
Highlights
Recent work in the field of organic catalysis has revealed the remarkable reactivity of Frustrated Lewis Pairs (FLP) [1]
Q-band and X-band pulsed electron paramagnetic resonance spectroscopic methods (EPR) in the solid state were employed to refine the parameters characterizing the anisotropic interactions present in six nitroxide radicals prepared by N,N addition of NO to various borane-phosphane frustrated Lewis pairs (FLPs)
All the EPR spectral analyses are done on echo detected field-sweep (EDFS) spectra
Summary
Recent work in the field of organic catalysis has revealed the remarkable reactivity of Frustrated Lewis Pairs (FLP) [1]. FLPs are molecular systems comprising both a Lewis acid and a Lewis base center, which would normally result in the formation of a covalent bond. If both Lewis centers are connected to bulky substituents, the covalent interactions between them are reduced (“frustration”), thereby imparting cooperative catalytic activity to the molecule. FLPs are of great interest in catalysis (e.g. for H2 activation) and for forming adducts with the ecologically problematic gases (CO, CO2, SO2, etc.) [2,3,4,5,6]. Intramolecular FLPs containing borane (Lewis acid) and phosphane (Lewis base) centers exhibit remarkable cooperative binding of such small molecules. When exposed to nitric oxide these B/P FLPs form heterocyclic chemically and thermally stable free aminoxyl radicals, which are interesting optical, magnetic and catalytic materials in their own right [5]
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