Abstract
1. The aminomethylation of phenyl-, p-tolyl-, and chloroferrocenes occurs predominantly in the unsubstituted cyclopentadienyl ring. The ratio of the amounts of hetero- and homoannular isomers is about 5∶1. 2. Methods were developed for the separation of hetero- and homoannular derivatives of (dimethylamino-methyl)ferrocenes on alumina impregnated with formamide and on Chromatographic paper. 3. 1-Methyl-1'-p-tolylferrocene was prepared.
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