Abstract
We describe here the amino-functionalization of multiwall carbon nanotubes (MWCNTs) and also its application as an adsorbent of solid phase extraction (SPE). The amino-functionalized MWCNTs have a good capacity to retain Hg2+, but the raw and purified MWCNTs are found not to adsorb Hg2+ ions. The amino-functionalized MWCNTs are prepared with amino-functionalization of purified MWCNTs by ethylenediamine. The physicochemical properties of purified and amino-functionalized MWCNTs are characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, and the Boehm titration. The amino-functionalized MWCNTs are selected as novel sorbents for the solid phase extraction of Hg2+. The amino-functionalized MWCNT-SPE method is used for the determination of Hg2+ from complex matrix including fish and real water samples. Effective parameters on Hg2+ retention such as pH, flowrate, nature of the eluent, the ionic strength, selectivity coefficient, and retention capacity are investigated. The enrichment factor and maximum capacity of the sorbent are 100 mL and 11.58 mg/g, respectively. The linear range, limit of detection, and relative standard deviation of the proposed method are 0.003 to 0.3 μg/L, 1.25×10−3 μg/L, and 2.23%, respectively. Selectivity experiments show that the adsorbents have a stronger specific retention for Hg2+ than Fe3+, Cu2+, Pb2+, Ni2+, Mn2+, Ca2+, and Mg2+.
Highlights
Mercury presents as different species in different environmental media including atmosphere, soil, sediment, natural waters, waste water, and water body
All of the IR spectra of multiwall carbon nanotubes (MWCNTs) are recorded by using KBr pellet method
There are peaks at ∼1159 and 1620 cm−1 in the IR spectra of oxidized MWCNTs corresponding to stretching of carbon-oxygen bond of lactone and asymmetric stretching of groups in the surface, respectively
Summary
Mercury presents as different species in different environmental media including atmosphere, soil, sediment, natural waters, waste water, and water body. The basic principle of SPE is the transfer of the analyte from the aqueous phase to bind to active sites of the adjacent solid phase It has several advantages over other techniques, including stability and reusability of the solid phase, reach of high preconcentration factors, easiness of separation and enrichment under dynamic conditions, no need for organic solvents which may be toxic, and minimal costs due to low consumption of reagents. These sorbents are conducted to determine the optimal chemical modification of MWCNTs in water and wastewater treatment
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