Abstract

AbstractThe synthesis of poly(alkylene phosphate)s with attached amino acids was elaborated. Two methods of coupling through P—NH bond were used. They were based on the direct reaction of amino acid esters or N,O‐bis(trimethylsilyl) substituted amino acids with poly(alkylene chlorophosphate)s. The assumed microstructure of the resulting polymers was confirmed by analysis of the 1H, 13C and 31P NMR spectra. Preliminary data on the hydrolytic stability of amino acids modified poly(alkylene phosphate)s are also given.

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