Abstract
The properties of β-cyanoenamines as analogs of amides are studied with derivatives of a rigid amino acid equivalent—Mcc = 1,2-diamino-3-cyanocyclopentene, prepared in two steps from methyl 2-(N-Boc-amino)-5-cyanopentanoate. Racemation of Mcc and incorporation into a cyclic pentapeptide are described.
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