Abstract
EDA-iodine complex with trialkylamine oxides in dichloromethane have been investigated spectrophotometrically. Thermodynamic (K c AD, —ΔG°) and spectral (ε λ AD) characteristics of these complexes were determined. The absorption band of iodine in the visible region was blue-shifted with a variable maximum, depending on the structure of the amine oxide. The K c AD and ε λ AD values were calculated using a modified method. A non-linear relationship K c AD = f( R), where R is the number of carbon atoms in the alkyl chain, was found.
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