Abstract
AbstractHydrogen energy, as a clean energy, is an important direction of new energy development. Here, amidoximated polyacrylonitrile (AOCF) with coordination ability was introduced by solution‐based blending method, and the electrocatalyst (N‐MoS2/AOCF‐C) with extended interlayer and multiphase structure was successfully synthesized. The structure characterization and experimental results showed that the spherical graphite mixed into the N‐MoS2 composite. The interlayer of the composite was significantly expanded and the N‐MoS2/C was randomly dispersed and anchored in AOCF matrix because the −OH and −NH2 of AOCF can form coordination bonds with Mo (IV) effectively. Therefore, the satisfactory hydrogen evolution reaction (HER) performance of N‐MoS2/AOCF‐C was attributed to the strong coordination bond effect and the addition of conducted carbon material. And the electrocatalyst displayed a lower overpotential (166 mV at a current density of 10 mA/cm2), a smaller Tafel slope (48.83 mV/dec), a larger electric double‐layer capacitance (84.19 mF/cm2) and nice stability.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
