Abstract

A development of washable PEDOT:PSS (poly(3,4-ethylenedioxythiophene) polystyrene sulfonate) polyamide textile-based electrodes is an interesting alternative to the traditional Ag/AgCl disposable electrodes, usually used in clinical practice, helping to improve medical assessment and treatment before apparition or progress of patients’ cardiovascular symptoms. This study was conducted in order to determine whether physical properties of PEDOT:PSS had a significant impact on the coated electrode’s electrocardiogram (ECG) signal quality, particularly after 50 washing cycles in a domestic laundry machine. Tests performed, included the comparison of two PEDOT:PSS solutions, in term of viscosity with emphasis on wetting tests, including surface tension and contact angle measurements. In addition, polyamide textile fabrics were used as substrate to make thirty electrodes and to characterize the amount of PEDOT:PSS absorbed as a function of time. The results showed that surface tension of PEDOT:PSS had a significant impact on the wetting of polyamide textile fabric and consequently on the absorbed amount. In fact, lower values of surface tension of the solution lead to low values contact angles between PEDOT:PSS and textile fabric (good wettability). Before washing, no significant difference has been observed among signal-to-noise ratios measured (SNR) for coated electrodes by the two PEDOT:PSS solutions. However, after 50 washing cycles, SNR decreased strongly for electrodes coated by the solution that had low viscosity, since it contained less solid contents. That was confirmed by scanning electron microscopy images (SEM) and also by analyzing the color change of electrodes based on the calculation of CIELAB color space coordinates. Moreover, spectral power density of recorded ECG signals has been computed and presented. All cardiac waves were still visible in the ECG signals after 50 washing cycles. Furthermore, an experienced cardiologist considered that all the ECG signals acquired were acceptable. Accordingly, our newly developed polyamide textile-based electrodes seem to be suitable for long-term monitoring. The study also provided new insights into the better choice of PEDOT:PSS formulation as a function of a specific process in order to manufacture cheaper electrodes faster.

Highlights

  • Research in the field of wearable devices and smart textiles is continuously growing

  • Results showed that for both PEDOT:PSS solutions, the contact angles are lower than 90◦, indicating that the polyamide textile fabric surface is wetted by these two solutions

  • The gain of solution 1 (S1) increased exponentially to reach 205 ± 8.9 mg in 300 s. It reaches only 177.3 ± 7.2 mg when using solution 2 (S2) solution. That for both PEDOT:PSS solutions, the contact angles are lower than 90°, indicating that the polyamide textile fabric surface is wetted by these two solutions

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Summary

Introduction

Research in the field of wearable devices and smart textiles is continuously growing. Standard wet silver/silver chloride (Ag/AgCl) is the most commonly used electrodes for ECG recording; they contain electrolytic conductive gel that reduces the skin-electrode contact impedance [7] They cannot be used for long-term monitoring, because hydrogel can provoke skin irritation after prolonged contact with the skin and the removal is painful [8,9]. The intention of this research is to understand the difference in physical properties of two different PEDOT:PSS solutions and the overall performance of the electrode made by these solutions especially after 50 washing cycles corresponding to one wash a week during one year To achieve these objectives, firstly, viscosity measurements were performed as well as surface tension of solutions and contact angle between the fabric and PEDOT:PSS.

PEDOT:PSS Solutions
Viscosity
Surface
Textile
Washing
Evaluation
CIELAB
50 Hz to filtered byECG
Physical Properties of PEDOT:PSS
Results and Discussion
Evaluation of Textile Electrodes in ECG Monitoring Before and After Washing
Conclusions
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