Abstract
Bis(diethylamino)[(methylthio)thiocarbonyl]carbenium salts ( 1), a carbenium ion carrying an α-thiocarbonyl group, shown ambident reactivities toward a series of nucleophiles. Thus, they reacted with a typically hard nucleophile, hydroxide, at the carbenium carbon atom, whereas they smoothly reacted with soft nucleophiles, such as carbon, nitrogen, sulfur, and phosphorus nucleophiles, at the thiocarbonyl sulfur atom.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
