Abstract

We synthesized aluminum-titanium-cobalt substituted epsilon iron oxide (ATC-ε-Fe2O3), ε-Al0.11Ti0.04Co0.05Fe1.80O3 (1), ε-Al0.14Ti0.04Co0.05Fe1.77O3 (2), and ε-Al0.26Ti0.04Co0.05Fe1.65O3 (3). The magnetic coercive field (Hc) values are 7.1 kOe (1), 6.5 kOe (2), and 4.4 kOe (3). Zero-field ferromagnetic resonance frequencies (fr) were observed at 112 GHz (1), 109 GHz (2), and 100 GHz (3) using terahertz time-domain spectroscopy. These Hc and fr values are suitable for high-density magnetic recording and high-frequency millimeter wave absorbers. Additionally, the present series is non-toxic, low-cost, and could be used as practical magnetic fillers for magnetic recording and millimeter wave absorber applications.

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