Abstract

Aluminumdodecatungstophosphate (AlPW 12O 40) a highly water tolerant, green Lewis acid has been applied as an efficient catalyst for the preparation of indole derivatives as bis(indolyl)methanes from carbonyl compounds via Friedel–Crafts alkylation and 3-substituted indoles via Michael addition of indole to α,β-unsaturated carbonyl compounds in CH 3CN at room temperature.

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