Aluminum Metal-Organic Frameworks with Photocatalytic Antibacterial Activity for Autonomous Indoor Humidity Control.

Abstract

There is an increasing need to maintain the indoor humidity at a comfortable and healthy level without relying on high energy-consuming and potentially germ-infested air-conditioning systems. Water adsorbents exhibiting reversible moisture adsorption/desorption ability as well as sufficient antibacterial activity are highly expected to achieve humidity control in an autonomous and safe way. Metal-organic frameworks (MOFs) featuring high porosity and designability show potential in meeting these requirements in a singular platform. Given the low toxicity and the rich abundance of aluminum in nature, a family of isoreticular Al-terephthalate-based MOFs were systematically evaluated in terms of the static and kinetic water adsorption/desorption and the photocatalytic bacteria-killing behavior. In particular, CAU-1-OH exhibits a desired working range (40-60% RH), a high working capacity (0.41 g g-1), an excellent cycle performance (500 cycles), and a high photocatalytic killing efficiency (99.94%) against Escherichia coli. As a proof of concept, the air filter prepared by coating CAU-1-OH on a commercial nonwoven fabric is capable of buffering against sudden humidity changes caused by the infiltration of outside air and effectively reducing the contamination of bioaerosol or particulate matter. The study significantly advanced the development of next-generation water adsorbents with antibacterial activity for residential humidity control.