Alternating current-enhanced carbon nanotubes hollow fiber membranes for membrane fouling control in novel membrane bioreactors

Abstract

A novel electro-assisted membrane bioreactor (EMBR) was built up with alternating current (AC) voltage applying on carbon nanotubes hollow fiber membranes (CNTs-HFMs) as the basic separation unit (AC-EMBR). Herein, a combination effect of electrostatic repulsion, electrochemical oxidation and translational motion behaviors was used to mitigate membrane fouling with +1.0 V for 1 min and −1.2 V for 1 min repeatedly applying on CNTs-HFMs. During the 73-day operation, the CNTs-HFMs in AC-EMBR exhibited a superior antifouling capability with a lower average fouling rate of 0.017 bar/d comparing to control groups, which were 0.021 bar/d in EMBR with CNTs-HFMs as cathode (C-EMBR), 0.025 bar/d in EMBR with CNTs-HFMs as anode (A-EMBR) and 0.029 bar/d in MBR without voltage, respectively. The AC potential led pollutants to loosely attach on membranes, which reduced irreversible fouling as well as reduced unrecoverable fouling levels. Bound extracellular polymeric substances (EPS) concentration in biomass of AC-EMBR was lower than those in the other reactors, which also contributed to suppressing membrane fouling. Meanwhile, an excellent effluent quality was obtained in AC-EMBR with COD removal rate higher than 96% and effluent NH4+-N concentration lower than 2 mg/L. Microbial community diversity has been promoted by AC electric field according to the microbial community analysis. The results of this study suggested the effectiveness of utilizing AC for membrane fouling mitigation and wastewater treatment in MBR systems.