Abstract
New five-membered ring π-conjugated polymers composed of 2,2′-bithiophene and 4,4′-dialkyl-2,2′-bithiazole units were prepared. The polymers were soluble in 1,2-dichlorobenzene and showed a UV–vis peak at about 490nm above 120°C. Cooling the solution led to the appearance of new UV–vis peaks at 550 and 600nm, which were considered to originate from self-assembled polymer molecules. Powder XRD (X-ray diffraction) data supported a well-stacked solid structure of the polymers and a highly ordered structure of a polymer film formed on a quartz glass substrate. These data revealed a strong tendency of the new polymers to self-assemble and to form an aligned structure on the surface of the substrates.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
