Abstract

Magnetoimpedance (MI) response of Co66Ni7Si7B20 ribbons treated with artificial urine with protein bovine serum albumin (BSA), artificial urine without protein BSA and healthy male urine was studied as a function of time of incubation. The maximum MI [(MI)m] values of the ribbons treated with artificial urine without protein (RTAU) after 3 h, 6 h, 12 h and 24 h of incubation are 30% (at 4 MHz), 15% (at 5 MHz), 14% (at 10 MHz) and 8% (at 13 MHz) respectively. On the other hand, the respective (MI)m values of the ribbons treated with artificial urine with protein (RTAUP) are 33% (at 4 MHz), 25% (at 5 MHz), 20% (at 8 MHz) and 15% (12 MHz). However (MI)m values of the ribbons treated with healthy male urine (RTHMU) after 4 h, 5 h, 10 h and 15 h of incubation are 71% (at 3 MHz), 57% (at 3 MHz), 25% (at 6 MHz) and 25% (at 5 MHz), respectively. The saturation magnetization (Ms) values of RTAU after 3 h, 6 h, 12 h and 24 h of incubation are 71 emu/g, 65 emu/g, 63 emu/g and 60 emu/g respectively whereas, the respective Ms values of RTAUP are 73 emu/g, 69 emu/g, 67 emu/g and 64 emu/g. The Ms values of RTHMU after 4 h, 5 h, 10 h and 15 h of incubation are 96 emu/g, 90 emu/g, 75 emu/g and 75 emu/g respectively. The decrease in Ms and (MI)m values in RTAU and RTAUP compared to as-quenched ribbon is related to the amounts of various elements etched out from the ribbons and increased surface roughness. The Ms and (MI)m values of RTHMU are seen to have increased after 4 h and 5 h of incubation, due to strain relaxation through removal of strain developed during rapid quenching of the ribbons. On the other hand, the Ms and (MI)m values of RTHMU after 10 h and 15 h have decreased due to deterioration of the surface of the ribbons and thus, increase in magnetic (surface) anisotropy. The decrease in (MI)m and MS of RTAU with the time of incubation are more rapid compared to that of RTAUP, probably due to the larger surface anisotropy due to rapid deterioration of the surface of the RTAU than in RTAUP. Asymmetry in MI profiles of RTAU, RTAUP and RTHMU was observed and is attributed to the non-uniform etching of the surface of the ribbons leading to pinning of the domain wall motion.

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