Abstract

Efficient inverted top-emitting organic light-emitting diode(ITOLED) using a thin Cs2CO3 layer modified Al as the reflective bottom cathode is demonstrated.With tris-(8-hydroxy-quinoline) aluminum(Alq3) as emitting layer and MoO3/Ag as semitransparent anode,the Al/Cs2CO3 based ITOLED shows a tune-on voltage of 3.6 V,luminance efficiency of 9.8 cd/A and 3.4 lm/W,which are much better than those(4.2 V,8.6 cd/A,2.85 lm/W) obtained from Mg∶Ag based ITOLED and those(5 V,5.5 cd/A,1.57 lm/W) obtained from bare Al based ITOLED.Electron-only devices research shows that a stronger electron-injection is obtained from Al/Cs2CO3 than Mg∶Ag and Al,which is attributed to the lower work function of Al/Cs2CO3 than Mg∶Ag and Al.The good performance of Al/Cs2CO3 based ITOLED is attributed to the efficient electron injection from the Al/Cs2CO3 cathode as well as a microcavity effect.

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