Abstract
The stereochemistry of the epcxidation of the title compound with t-BuOOH catalysed by VO(acac) 2 is subject to exclusive homoallylic control. Secondary allylic alcohols in the side chain regain their normal controlling influence over diastereoselection only when the homoallylic group is blocked.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.