Allylic geminal diacetates as a a 1,a 3 synthon. A convenient synthesis of bicyclo[3.3.1]nonan-9-one derivatives

Abstract

2-Acetoxy bicyclo[3.3.1]nonan-9-one derivatives could be systhesized from the reaction of allylic 1,1-diol diacetates(1) with pyrrolidine enamine of cyclohexanone under the catalysis of palladium complex in one step.