Alleviating the burden of ion exchange brine in water treatment: From operational strategies to brine management

Abstract

Ion exchange (IX) using synthetic resins is a cost-efficient technology to cope with a wide range of contaminants in water treatment. However, implementing IX processes is constrained by the regeneration of IX resins that generates a highly concentrated brine (i.e., IX brine), the disposal of which is costly and detrimental to ecosystems. In an effort to make the application of IX resins more sustainable in water treatment, substantial research has been conducted on the optimization of IX resins operation and the management of IX brine. The present review critically evaluates the literature surrounding IX operational strategies and IX brine management which can be used to limit the negative impacts arising from IX brine. To this end, we first analyzed the physicochemical characteristics of brines from the regeneration of IX resins. Then, we critically evaluated IX operational strategies that facilitate brine management, including resin selection, contactor selection, operational modes, and regeneration strategies. Furthermore, we analyzed IX brine management strategies, including brine reuse and brine disposal (without or with treatment). Finally, a novel workflow for the IX water treatment plant design that integrates IX operational strategies and IX brine management is proposed, thereby highlighting the areas that make IX technology more sustainable for water treatment.