All Aqueous Synthesis of Silica Encapsulated Quantum Dots with Functional Shells

Abstract

All-aqueous synthesis of silica-encapsulated quantum dots with functional shells Huanhuan Feng[abc], Jan Bart ten Hove[d], Tingting Zheng[ae], Aldrik H. Velders[d] and Joris Sprakel∗[a] We present a simple yet versatile method for encapsulating water-dispersed quantum dots (QDs) in a silica shell. As our approach, does not require ligand exchange, the colloidal stability of the quantum dots is maintained throughout the process, which results in monodisperse core-shell particles of individual quantum dots with a well-defined silica shell whose thickness can be accurately controlled. While other methods often result in a reduction of luminescence, our approach can retain all or even increases the quantum efficiency of the semiconductor dots. We also show how amine-functional groups can be expressed at the surface of the silica shell, while retaining QD photoluminescence properties, allowing further surface functionalization. Finally, we demonstrate the versatility of this strategy by including dopants into the silica shells to tailor the spectral response of the core-shell particles by energy transfer. [a] Physical Chemistry and Soft Matter, Wageningen University & Research, Stippeneng 4, 6708 WE Wageningen, the Netherlands [b] Dutch Polymer Institute (DPI), P.O. Box 902, 5200 AX Eindhoven, the Netherlands [c] School of Materials Science and Engineering, Harbin Institute of Technology (Shenzhen), China [d] Laboratory of BioNanoTechnology, Wageningen University & Research, Bornse Weilanden 9,6708 WG Wageningen, The Netherlands [e] Shenzhen Key Laboratory for Drug Addiction and Medication Saftey, Department of Ultrasound, Peking University Shenzhen Hospital & Biomedical Research Institute, Shenzhen-PKU-HKUST Medical Center, Shenzhen 518036, China.