Abstract
Reaction of dehydromonocrotaline ( 3), the putative toxic metabolite of the carcinogenic pyrrolizidine alkaloid monocrotaline ( 2), with various nucleosides proceeded mostly at the C-9″ position of 3 to give several nitrogen atom-alkylated nucleosides including N-7 alkylated 2′-deoxyguanosine 14.
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