Abstract
Baylis-Hillman reaction was used to afford a series of four alkyl α-hydroxymethyl acrylates, methyl (MHMA), ethyl (EHMA), isopropyl (iPrHMA), and n-butyl (nBHMA) α-hydroxymethyl acrylate, with tunable water solubility. MHMA and EHMA with high water solubility were identified as suitable candidates for aqueous dispersion polymerization-induced self-assembly (PISA). PISA of EHMA and MHMA using poly(ethylene glycol) macromolecular chain transfer agents (PEG45-CTA and PEG113-CTA) was investigated under either thermal or photoinitiation at 40-70 °C. Photo-PISA at low temperatures provided both morphological transition and PEG45-PEHMAx block copolymers with narrow molecular weight distributions. iPrHMA with moderate water solubility was used for dispersion-emulsion polymerization with the formation of vesicles being observed.
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