Abstract
(2-Alkoxy-3-phenylpropyl)trichlorotellanes were synthesized by regioselective reaction of tellurium tetrachloride with allylbenzene in the system MeOH–CH2Cl2, as well as by nucleophilic substitution of chlorine in trichloro(2-chloro-3-phenylpropyl)tellane in MeOH–CH2Cl2 and EtOH–CHCl3. Allylbenzene reacted with tellurium tetrabromide on heating in methanol or ethanol. The reduction of (2-alkoxy-3-phenylpropyl) trihalotellanes with NaBH4 in H2O–THF gave 1,2-bis(2-alkoxy-3-phenylpropyl)ditellanes.
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