Abstract

Palladium/carboxylic acid-catalyzed alkenylation of heteroarenes and electron-deficient arenes using alkynes underwent C(sp2)–H bond activation in arene substrates to give the corresponding alkenylarenes straightforwardly. The versatility of this transformation is demonstrated by the double alkenylation of functionalized thiophenes and 5,6-difluorobenzothiadiazole with alkynes and provides a one-step access to vinylene-arylene-vinylene units.

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