Alkaline leaching of nickel bearing ammonium jarosite precipitate using KOH, NaOH and NH4OH in the presence of EDTA and Na2S

Abstract

Jarosite precipitates produced in base metal refineries contain substantial amounts of base metals. The dissolution of nickel from the jarosite precipitate was investigated in alkaline medium (KOH, NaOH and NH4OH) at laboratory-scale in the presence of EDTA as a complexing agent and Na2S as reducing agent. The leaching efficiency of nickel was 82.4%, 84.5% and 88.9% in NaOH, KOH and NH4OH respectively in the presence of 0.1M EDTA–Na2S, pH9–10, using −75μm of ammonium jarosite precipitate at 250rpm, 45°C, 5% solids and leaching time of 4h. Thermodynamic feasibility was explored using Medusa software and the kinetics of the dissolution process was studied using the shrinking core model. The results show that the dissolution process is second order and diffusion controlled. The activation energy was found to be 32.34, 35.31 and 31.52kJ/mol in KOH, NaOH and NH4OH mediums respectively in the temperature ranges between 25 and 45°C. The effects of EDTA–Na2S concentration, particle size, pH, solid–liquid ratio, stirring speed, temperature and contact time were explored.